Hydrogenation of catalyzed d-glucose by complex of ruthenio containing triarilphosphines ligands in the middle homogeneo and bifasico-aquoso
Keywords:
triarilfosfina, biphasic-aqueous, ruthenium, D-glucose, sorbitol, triarylphosphineAbstract
In this investigation the hydrogenation of D-glucose to sorbitol (D-glucitol), a sweetener for industrial use, was carried out using as catalytic precursors ruthenium systems containing triarylphosphine ligands, such as triphenylphosphine (PPh 3), tri (p-) toluyl) phosphine [P (p-tol) 3], triphenylphosphine monosulfonated (TFFMS) and trisulfonated triphenylphosphine (TFFTS), both in homogeneous (water) and biphasic-aqueous medium.
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